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Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

Frontiers of Chemical Science and Engineering 2013, Volume 7, Issue 2,   Pages 139-144 doi: 10.1007/s11705-013-1323-8

Abstract: A macro reaction kinetic model was established for the HDS of CGO in the slurry reactor.

Keywords： coker gas oil     hydrodesulfurization     slurry reactor     reaction kinetic model    

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Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and

Frontiers in Energy 2022, Volume 16, Issue 2,   Pages 263-276 doi: 10.1007/s11708-021-0791-7

Abstract: Four kinetic models (the Glarborg model, Shrestha model, Mei model, and Han model) were compared andPathway, sensitivity and radical pool analysis are conducted to find out the deep kinetic insight on

Keywords： ammonia mixed with syngas     laminar flame speed     kinetic model     sensitivity analysis     pathway analysis    

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Kinetic study of the methanol to olefin process on a SAPO-34 catalyst

Mehdi SEDIGHI,Kamyar KEYVANLOO

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 3,   Pages 306-311 doi: 10.1007/s11705-014-1440-z

Abstract: In this paper, a new kinetic model for methanol to olefin process over SAPO-34 catalyst was developedThe kinetic model fits well to the experimental data obtained in a fixed bed reactor.Using this kinetic model, the effect of the most important operating conditions such as temperature,

Keywords： methanol to olefin     SAPO-34     kinetic modeling     elementary step    

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Simultaneous removal of NO and chlorobenzene on VO/TiO granular catalyst: Kinetic study and performance

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 4, doi: 10.1007/s11783-020-1363-5

Abstract:

• A V2O5/TiO2 granular catalyst for simultaneous removal of NO and chlorobenzene.

Keywords： NOx     Chlorobenzene     Simultaneous removal     Kinetic study     Performance prediction     V<    

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The kinetic study of light alkene syntheses by CO 2 hydrogenation over Fe-Ni catalysts

Yaling ZHAO, Li WANG, Xiwei HAO, Jiazhou WU,

Frontiers of Chemical Science and Engineering 2010, Volume 4, Issue 2,   Pages 153-162 doi: 10.1007/s11705-009-0241-2

Abstract: A kinetics model of CO hydrogenation over iron-nickel catalysts was developed based on the detailed mechanism of alkenes re-adsorption and secondary reaction. The corresponding kinetical experiments are conducted in a continuous fixed bed reactor. The effect of reaction conditions on catalyst performance was analyzed according to the results of orthogonal experiments. The results of the experiments show that more methane in products can be obtained with iron-nickel catalysts, the trend of which is consistent with the thermodynamic analysis. However, the content of alkenes in products is equivalent with that of alkanes. This shows that the reaction is controlled by kinetics. In all, the results of the experiments also substantiate that the model can give a good representation of the reaction mechanism of CO hydrogenation over iron-nickel catalysts. The parameters of this model give a better explanation for the question why the iron-nickel catalysts have a higher selectivity toward alkenes compared with other iron-based catalysts.

Keywords： representation     corresponding     orthogonal     thermodynamic     consistent    

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and sulfur co-doped carbon nanotubes for effective desulfurization of liquid phases: Equilibrium & kineticstudy

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 5, doi: 10.1007/s11783-021-1397-3

Abstract:

• Synthesis of NS-CNTS is used in a high desulfurization performance.

Keywords： Dibenzothiophene (DBT)     Tertiary methyl mercaptan     Adsorption     Carbon nano tube (CNT)     Desulfurization     Doping    

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Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

Frontiers of Environmental Science & Engineering 2019, Volume 13, Issue 5, doi: 10.1007/s11783-019-1152-1

Abstract: Adsorption capacities based on kinetic modeling were observed as Cr>Cu>Ni>Zn.adjustment, but as an alternative to this method, the electrocoagulation process has investigated in this studyIn the process where kinetic modeling was applied, it was observed that the heavy metal removal mechanism

Keywords： Electrochemical treatment     Heavy metals     Kinetic modeling     Pseudo first order kinetic     Pseudo second orderkinetic    

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Thermogravimetric kinetic analysis of

SUKARNI,SUDJITO,Nurkholis HAMIDI,Uun YANUHAR,I.N.G. WARDANA

Frontiers in Energy 2015, Volume 9, Issue 2,   Pages 125-133 doi: 10.1007/s11708-015-0346-x

Abstract: The kinetic parameters were evaluated by using Kissinger and Ozawa methods.

Keywords： Nannochloropsis oculata     combustion     kinetic parameters     air atmosphere     thermogravimetric    

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photoreduction process in a laboratory-scale photoreactor by computational fluid dynamic and reaction kinetic

Frontiers of Chemical Science and Engineering 2022, Volume 16, Issue 7,   Pages 1149-1163 doi: 10.1007/s11705-021-2096-0

Abstract: computational fluid dynamic model combined with the novel carbon dioxide photoreduction intrinsic reaction kineticdifferent carbon dioxide and water moisture partial pressures was then modeled based on the intrinsic kinetic

Keywords： carbon dioxide photoreduction     computational fluid dynamic simulation     kinetic model     Langmuir adsorption    

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for damage detection in functionally graded carbon nanotube-reinforced composite plates using modal kinetic

Frontiers of Structural and Civil Engineering 2021, Volume 15, Issue 6,   Pages 1453-1479 doi: 10.1007/s11709-021-0767-z

Abstract: The elemental modal kinetic energy (MKE) values, calculated from natural frequencies and translational

Keywords： feed-forward neural networks     functionally graded carbon nanotube-reinforced composite plates     modal kinetic    

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Application of micro-genetic algorithm for calibration of kinetic parameters in HCCI engine combustion

HUANG Haozhong, SU Wanhua

Frontiers in Energy 2008, Volume 2, Issue 1,   Pages 86-92 doi: 10.1007/s11708-008-0003-8

Abstract: highly effective optimization method, is applied to calibrate to a newly developed reduced chemical kineticThe seven kinetic parameters of the calibrated model are determined using a combination of the Micro-Geneticthe autoignition predictions of the calibrated model agree better with those of the detailed chemical kineticThe results of this study have demonstrated that the mGA is an effective tool to facilitate the calibrationof a large number of kinetic parameters in a reduced kinetic model.

Keywords： homogeneous     different     combustion     autoignition     compression    

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Prediction of high-density polyethylene pyrolysis using kinetic parameters based on thermogravimetric

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 1, doi: 10.1007/s11783-023-1606-3

Abstract:

● Reducting the sampling frequency can enhance the modelling process.

Keywords： HDPE     Pyrolysis     Kinetics     Thermogravimetric     ANOVA     Artificial neural network    

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Oxidation-extraction desulfurization of model oil over Zr-ZSM-5/SBA-15 and kinetic study

Chuanzhu LU,Hui FU,Huipeng LI,Hua ZHAO,Tianfeng CAI

Frontiers of Chemical Science and Engineering 2014, Volume 8, Issue 2,   Pages 203-211 doi: 10.1007/s11705-014-1420-3

Abstract: ZSM-5/SBA-15 composite molecular sieves were synthesized using post-synthesis method and characterized by X-ray diffraction and N adsorption-desorption. The oxidative-extration desulfurization of model oil was investigated by using hydrogen peroxide as the oxidant, tetrabutyl ammonium bromide as phase transfer catalyst, dimethyl sulfoxide as extractant, and Zr-ZSM-5/SBA-15, Ag-ZSM-5/SBA-15, Ce-ZSM-5/SBA-15 as catalyst. Under the optimal conditions, the desulfurization rate decreases in the order: Zr-ZSM-5/SBA-15>Ce-ZSM-5/SBA-15>Ag-ZSM-5/SBA-15. The highest desulfurization rate is 84.53% under the catalysis of Zr-ZSM-5/SBA-15. Kinetics analysis shows that the reaction is pseudo-first-order with the activation energy of 44.23 kJ/mol.

Keywords： composite molecular sieve     oxidation desulfuration     extraction     kinetic    

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Kinetic energy based model assessment and sensitivity analysis of vortex induced vibration of segmental

Nazim Abdul NARIMAN

Frontiers of Structural and Civil Engineering 2017, Volume 11, Issue 4,   Pages 480-501 doi: 10.1007/s11709-017-0435-5

Abstract: parameters (wind speed, deck streamlined length and dynamic viscosity of the air) are dedicated to studytheir effects on the kinetic energy of the system in addition to the shapes and patterns of the vorticesLatin hypercube experimental method is dedicated to generate the surrogate models for the kinetic energyThe kinetic energy approach performed very well in revealing the rational effects and the roles of each

Keywords： vortex induced vibration     reynolds number     kinetic energy     vorticity     latin hypercube sampling    

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Catalytic combustion of methane over a highly active and stable NiO/CeO

Xiuhui Huang, Junfeng Li, Jun Wang, Zeqiu Li, Jiayin Xu

Frontiers of Chemical Science and Engineering 2020, Volume 14, Issue 4,   Pages 534-545 doi: 10.1007/s11705-019-1821-4

Abstract: The results of a kinetics study indicated that the reaction order was about 1.07 for CH and about 0.10

Keywords： methane combustion     NiO/CeO2 catalyst     interaction     oxygen vacancy     kinetic study    

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Title Author Date Type Operation

Kinetic study of hydrodesulfurization of coker gas oil in a slurry reactor

Haiding XIANG, Tiefeng WANG

Journal Article

Experimental and kinetic study on laminar flame speeds of ammonia/syngas/air at a high temperature and

Journal Article

Kinetic study of the methanol to olefin process on a SAPO-34 catalyst

Mehdi SEDIGHI,Kamyar KEYVANLOO

Journal Article

Simultaneous removal of NO and chlorobenzene on VO/TiO granular catalyst: Kinetic study and performance

Journal Article

The kinetic study of light alkene syntheses by CO 2 hydrogenation over Fe-Ni catalysts

Yaling ZHAO, Li WANG, Xiwei HAO, Jiazhou WU,

Journal Article

and sulfur co-doped carbon nanotubes for effective desulfurization of liquid phases: Equilibrium & kineticstudy

Journal Article

Electrocoagulation process for the treatment of metal-plating wastewater: Kinetic modeling and energy

Fatih Ilhan, Kubra Ulucan-Altuntas, Yasar Avsar, Ugur Kurt, Arslan Saral

Journal Article

Thermogravimetric kinetic analysis of

SUKARNI,SUDJITO,Nurkholis HAMIDI,Uun YANUHAR,I.N.G. WARDANA

Journal Article

photoreduction process in a laboratory-scale photoreactor by computational fluid dynamic and reaction kinetic

Journal Article

for damage detection in functionally graded carbon nanotube-reinforced composite plates using modal kinetic

Journal Article

Application of micro-genetic algorithm for calibration of kinetic parameters in HCCI engine combustion

HUANG Haozhong, SU Wanhua

Journal Article

Prediction of high-density polyethylene pyrolysis using kinetic parameters based on thermogravimetric

Journal Article

Oxidation-extraction desulfurization of model oil over Zr-ZSM-5/SBA-15 and kinetic study

Chuanzhu LU,Hui FU,Huipeng LI,Hua ZHAO,Tianfeng CAI

Journal Article

Kinetic energy based model assessment and sensitivity analysis of vortex induced vibration of segmental

Nazim Abdul NARIMAN

Journal Article

Catalytic combustion of methane over a highly active and stable NiO/CeO

Xiuhui Huang, Junfeng Li, Jun Wang, Zeqiu Li, Jiayin Xu

Journal Article